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The quadruple-bond complex, [Mo2(p-O2CC6H4CF3)4·2THF], crystallizes in the triclinic space group P with intercalated pentane/THF lattice solvent molecules. The electron-withdrawing group on the paddlewheel carboxylate together with the axial THF molecules… Click to show full abstract
The quadruple-bond complex, [Mo2(p-O2CC6H4CF3)4·2THF], crystallizes in the triclinic space group P with intercalated pentane/THF lattice solvent molecules. The electron-withdrawing group on the paddlewheel carboxylate together with the axial THF molecules lead to a slight lengthening of the metal–metal bond, as predicted by Cotton.
Keywords:
structure trifluoromethyl;
trifluoromethyl benzoato;
crystal structure;
quadruple bonded;
bonded dimolybdenum;
benzoato quadruple
Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022
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Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!