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Tetranuclear copper(II) complex of 2-hydroxy-N,N′-bis[1-(2-hydroxyphenyl)ethylidene]propane-1,3-diamine

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In the title Schiff base tetranuclear copper(II) complex, two discrete environments are present in the structure: CuNO4 and CuNO3. Two copper(II) cations are situated in distorted square-pyramidal environment, while two… Click to show full abstract

In the title Schiff base tetranuclear copper(II) complex, two discrete environments are present in the structure: CuNO4 and CuNO3. Two copper(II) cations are situated in distorted square-pyramidal environment, while two copper(II) cations are located in a slightly square-planar geometry. One bridging acetate group acting in an η1:η1-μ2-mode connects two copper(II) ions, while another bridging acetate group connects three copper(II) ions in an η1:-η2–μ3-mode.

Keywords: copper complex; tetranuclear copper; copper; complex hydroxy; two copper

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022

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