Nickel(II) Schiff base complexes containing thiolate S and polyamine N donor atoms exhibit electrocatalytic activity for proton reduction. The piperazine moiety in the Schiff base ligand gives a smaller bite… Click to show full abstract
Nickel(II) Schiff base complexes containing thiolate S and polyamine N donor atoms exhibit electrocatalytic activity for proton reduction. The piperazine moiety in the Schiff base ligand gives a smaller bite angle, which is effective in reducing the overpotential.
               
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