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Crystal structures and electrochemical properties of nickel(II) complexes with N,N′,N′′,S-tetradentate Schiff base ligands

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Nickel(II) Schiff base complexes containing thiolate S and polyamine N donor atoms exhibit electrocatalytic activity for proton reduction. The piperazine moiety in the Schiff base ligand gives a smaller bite… Click to show full abstract

Nickel(II) Schiff base complexes containing thiolate S and polyamine N donor atoms exhibit electrocatalytic activity for proton reduction. The piperazine moiety in the Schiff base ligand gives a smaller bite angle, which is effective in reducing the overpotential.

Keywords: structures electrochemical; electrochemical properties; crystal structures; properties nickel; base; schiff base

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022

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