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The reaction of [Cu(CH3CN)4](BF4) with 1-methyl-1,3-imidazolidine-2-thione {SC3H4(NMe) NH} forms the one-dimensional coordination polymer [Cu4(κ5:L 1—N—S—N—L 1)2(κ1:L 1—NH)2(κ2: L 1—NH)2] n (BF4)4n {L 1 = SC3H4(NMe)NH} with sulfur-bridged {CuI 4S10} n… Click to show full abstract
The reaction of [Cu(CH3CN)4](BF4) with 1-methyl-1,3-imidazolidine-2-thione {SC3H4(NMe) NH} forms the one-dimensional coordination polymer [Cu4(κ5:L 1—N—S—N—L 1)2(κ1:L 1—NH)2(κ2: L 1—NH)2] n (BF4)4n {L 1 = SC3H4(NMe)NH} with sulfur-bridged {CuI 4S10} n central cores.
Keywords:
coordination polymer;
bridged cui;
sulfur bridged;
methyl imidazolidine;
imidazolidine thione;
one dimensional
Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022
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Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!