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Crystal structure and Hirshfeld surface analysis of ethyl (3E)-5-(4-chlorophenyl)-3-{[(4-chlorophenyl)formamido]imino}-7-methyl-2H,3H,5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate

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The thiazole ring is planar while the pyrimidine unit fused to it adopts a screw-boat conformation In the crystal, N—H⋯N plus C—H⋯N hydrogen bonds form helical chains along the b-axis… Click to show full abstract

The thiazole ring is planar while the pyrimidine unit fused to it adopts a screw-boat conformation In the crystal, N—H⋯N plus C—H⋯N hydrogen bonds form helical chains along the b-axis direction, which are linked into thick sheets parallel to the bc plane by C—H⋯O hydrogen bonds and π–π interactions between the formamido carbonyl groups and the thiazole rings.

Keywords: pyrimidine; chlorophenyl; surface analysis; structure hirshfeld; crystal structure; hirshfeld surface

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022

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