The title compound, Ba3[Sn(OH)6][SeO4]2·3H2O, was prepared by mimicking geochemical crystallization processes, and the hexagonal crystal structure determined. Its hierarchical structure comes from four different primary building units, setting up secondary… Click to show full abstract
The title compound, Ba3[Sn(OH)6][SeO4]2·3H2O, was prepared by mimicking geochemical crystallization processes, and the hexagonal crystal structure determined. Its hierarchical structure comes from four different primary building units, setting up secondary building units that are arranged into layers via their {BaO9} coordination polyhedra and cross-linked with the SBUs of adjacent layers via common [Sn(OH)6]2− ions.
               
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