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Crystal structure of bis{3-(3,4-dimethylphenyl)-5-[6-(1H-pyrazol-1-yl)pyridin-2-yl]-4H-1,2,4-triazol-4-ido}iron(II) methanol disolvate

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The title compound, a charge-neutral bis{2-(3,4-dimethylphenyl)-4H-1,2,4-triazol-3-ato)-6-(1H-πyrazol-1-yl)pyridine} iron(II) complex dimethanol solvate, is a low-spin complex with a moderately distorted pseudooctahedral coordination environment of the metal ion. As a result of the… Click to show full abstract

The title compound, a charge-neutral bis{2-(3,4-dimethylphenyl)-4H-1,2,4-triazol-3-ato)-6-(1H-πyrazol-1-yl)pyridine} iron(II) complex dimethanol solvate, is a low-spin complex with a moderately distorted pseudooctahedral coordination environment of the metal ion. As a result of the cone shape, the molecules are stacked in mono-periodic columns that are bound by weak hydrogen bonds into di-periodic layers, which, in turn, are arranged in a three-dimensional lattice bound by weak interlayer interactions.

Keywords: bis; bis dimethylphenyl; iron; triazol; crystal structure

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022

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