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Crystal structures of two 1,2,3,4-tetrahydronaphthalenes obtained during efforts towards the total synthesis of elisabethin A

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The molecular structures of methyl (R)-3-{(1R,4S)-6-methoxy-4,7-dimethyl-5,8-bis[(triisopropylsilyl)oxy]-1,2,3,4-tetrahydronaphthalen-1-yl}butanoate and methyl (E)-3-{(1R,4S)-8-hydroxy-6-methoxy-4,7-dimethyl-5-[(triisopropylsilyl)oxy]-1,2,3,4-tetrahydronaphthalen-1-yl}acrylate exhibit the same configurations of the stereo centres in the 1,2,3,4-tetrahydronaphthalene moiety, the conformation of which is nearly identical in the… Click to show full abstract

The molecular structures of methyl (R)-3-{(1R,4S)-6-methoxy-4,7-dimethyl-5,8-bis[(triisopropylsilyl)oxy]-1,2,3,4-tetrahydronaphthalen-1-yl}butanoate and methyl (E)-3-{(1R,4S)-8-hydroxy-6-methoxy-4,7-dimethyl-5-[(triisopropylsilyl)oxy]-1,2,3,4-tetrahydronaphthalen-1-yl}acrylate exhibit the same configurations of the stereo centres in the 1,2,3,4-tetrahydronaphthalene moiety, the conformation of which is nearly identical in the two molecules.

Keywords: two tetrahydronaphthalenes; structures two; obtained efforts; crystal structures; efforts towards; tetrahydronaphthalenes obtained

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2023

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