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Crystal structure, Hirshfeld surface analysis and DFT study of (5E,5′E,6Z,6′Z)-6,6′-[ethane-1,2-diylbis(azanylylidene)]bis{5-[2-(4-fluorophenyl)hydrazono]-3,3-dimethylcyclohexanone} 2.5-hydrate

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The title compound was obtained by the condensation of ethylenediamine and (5E,5E,6Z,6Z)-6,6-[ethane-1,2-diylbis(azanylylidene)]bis{5-[2-(4-fluorophenyl)hydrazono)-3,3-dimethylcyclohexanone} in ethanol and crystallized as a 1:2.5 hydrate containing two different conformers stabilized by intramolecular N—H⋯N and linked… Click to show full abstract

The title compound was obtained by the condensation of ethylenediamine and (5E,5E,6Z,6Z)-6,6-[ethane-1,2-diylbis(azanylylidene)]bis{5-[2-(4-fluorophenyl)hydrazono)-3,3-dimethylcyclohexanone} in ethanol and crystallized as a 1:2.5 hydrate containing two different conformers stabilized by intramolecular N—H⋯N and linked by O—H⋯O (involving the water molecules) hydrogen bonds.

Keywords: ethane diylbis; azanylylidene bis; diylbis azanylylidene; bis fluorophenyl; fluorophenyl hydrazono; hydrazono dimethylcyclohexanone

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2023

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