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Seeking new, highly effective thermoelectrics

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Operating across a wide temperature range is a priority for thermoelectric materials Thermoelectric technology can directly and reversibly convert heat to electrical energy. Although thermoelectric energy conversion will never be… Click to show full abstract

Operating across a wide temperature range is a priority for thermoelectric materials Thermoelectric technology can directly and reversibly convert heat to electrical energy. Although thermoelectric energy conversion will never be as efficient as a steam engine (1), improving thermoelectric performance can potentially make a technology commercially competitive. Thermoelectric conversion efficiency is estimated by the so-called dimensionless figure of merit, ZT = S2σT/κ, where S, σ, T, and κ denote the Seebeck coefficient, electrical conductivity, working temperature, and thermal conductivity, respectfully . These parameters are strongly coupled, and improving the final ZT is challenging as a result. Strategies for boosting thermoelectric performance include nanostructuring, band engineering, nanomagnetic compositing, high-throughput screening, and others (2). Many of these strategies create a high ZT in a narrow range of temperatures, limiting the overall energy conversion. Finding materials with wider operating temperature ranges may require rethinking development strategies.

Keywords: temperature; new highly; energy; highly effective; seeking new; effective thermoelectrics

Journal Title: Science
Year Published: 2020

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