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Garnet Solid Solution (Y1 – xBix)3Fe2.5Ga2.5O12

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Samples of composition (Y1–xBix)3Fe2.5Ga2.5O12 (0 ≤ х ≤1), synthesized by the polyvinyl alcohol gel combustion method, have been studied by X-ray diffraction. It has been shown that the homogeneity range… Click to show full abstract

Samples of composition (Y1–xBix)3Fe2.5Ga2.5O12 (0 ≤ х ≤1), synthesized by the polyvinyl alcohol gel combustion method, have been studied by X-ray diffraction. It has been shown that the homogeneity range of the solid solution persists up to the composition Y1.5Bi1.5Fe2.5Ga2.5O12. This allows to consider gallium- substituted bismuth yttrium ferrites with an equimolar Fe: Ga ratio as stable materials for possible use in magnetooptics.

Keywords: 5ga2 5o12; xbix 3fe2; garnet solid; 3fe2 5ga2; solid solution

Journal Title: Doklady Chemistry
Year Published: 2018

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