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С21n‑alkylbenzene and 1‑n‑alklylnaphthalene in Oils: Isotope Effect during Cyclization/Aromatization?

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Abstract—Carbon isotope composition was analyzed in С21n‑alkylbenzene and n‑alklylnaphthalene from five Upper Devonian oils of the Timan–Pechora Basin. In spite of the variations in carbon isotope composition, the difference in… Click to show full abstract

Abstract—Carbon isotope composition was analyzed in С21n‑alkylbenzene and n‑alklylnaphthalene from five Upper Devonian oils of the Timan–Pechora Basin. In spite of the variations in carbon isotope composition, the difference in δ13C between n‑alkylbenzene and n‑alklylnaphthalene is relatively constant and accounts for, on average, 2.7‰. It is generally accepted that these compounds were derived from a common source. Thus, the revealed carbon isotope fractionation is related to the cyclization and aromatization of aliphatic chain.

Keywords: 21n alkylbenzene; alkylbenzene alklylnaphthalene; cyclization aromatization; alklylnaphthalene

Journal Title: Geochemistry International
Year Published: 2020

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