Abstract —Powders of the double borate PbCd2B6O12 and PbCd2 –xMnxB6O12 solid solutions have been prepared by solid-state reactions and the crystallographic characteristics of the synthesized phases have been determined (sp.… Click to show full abstract
Abstract —Powders of the double borate PbCd2B6O12 and PbCd2 –xMnxB6O12 solid solutions have been prepared by solid-state reactions and the crystallographic characteristics of the synthesized phases have been determined (sp. gr. P21/n). Using differential scanning calorimetry and X-ray diffraction, the PbCd2B6O12 compound has been shown to melt incongruently at 734°C. The effect of activator ion concentration on the thermoluminescence intensity in phases of variable composition at temperatures in the range 25–400°C has been studied for the first time. The sample containing 5 mol % Mn2+ ions has been shown to offer the highest luminescence brightness in the visible spectral region.
               
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