Photo from wikipedia
A kinetic study of reaction of alkene arylation by anhydrides of aromatic acids (modified Mizoroki–Heck reaction) was carried out using differential selectivity as the main measured parameter. The results obtained… Click to show full abstract
A kinetic study of reaction of alkene arylation by anhydrides of aromatic acids (modified Mizoroki–Heck reaction) was carried out using differential selectivity as the main measured parameter. The results obtained under conditions of competition between a pair of alkenes or a pair of aromatic anhydrides point to the occurrence of the reaction via a homogeneous mechanism of catalysis analogously to a conventional variant of reaction with aryl halides as arylating reagents. The hypothesis that the active catalyst is homogeneous agrees with the results of kinetic studies of processes of catalyst formation and deactivation.
Journal Title: Kinetics and Catalysis
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!