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Electrical resistivity and thermal electromotive force of Ni75V25, Ni72V28, and Ni67V33 alloys at high temperatures

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The temperature dependences of the electrical resistivity and thermal electromotive force (thermal e.m.f.) of the Ni–25 at % V, Ni–28 at % V, and Ni–33 at % V alloys in… Click to show full abstract

The temperature dependences of the electrical resistivity and thermal electromotive force (thermal e.m.f.) of the Ni–25 at % V, Ni–28 at % V, and Ni–33 at % V alloys in a temperature range of 300–1600 K have been reported; the dependences have been measured during slow heating and cooling of quenched and annealed samples. It has been shown that, near the order–disorder phase-transformation temperature, the temperature dependences of the electrical resistivity of the Ni75V25 and Ni67V33 alloys demonstrate a kink (second-order phase transition) and a jump (first-order phase transition), respectively. The behavior of the experimental dependences is discussed in terms of the band Mott s–d scattering model.

Keywords: resistivity; thermal electromotive; electromotive force; ni67v33 alloys; resistivity thermal; electrical resistivity

Journal Title: Physics of Metals and Metallography
Year Published: 2017

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