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AbstractPerovskite-like phases AMn3V4O12 (A = Ca, Ce, and Sm) were prepared under borothermic conditions (p = 7.0–9.0 GPa, T = 700–1100°C). Their X-ray diffraction structure (space group Im$$\bar 3$$3¯ ,… Click to show full abstract
AbstractPerovskite-like phases AMn3V4O12 (A = Ca, Ce, and Sm) were prepared under borothermic conditions (p = 7.0–9.0 GPa, T = 700–1100°C). Their X-ray diffraction structure (space group Im$$\bar 3$$3¯ , Z = 2) was determined, and unit cell parameters were calculated: for CaMn3V4O12: а = 7.40824(3) Å, for SmMn3V4O12: а = 7.45280(8) Å, and for CeMn3V4O12: а = 7.46965(4) Å. The temperature-dependent electrical resistivity (10–300 K) and magnetic susceptibility (2–300 K) of the prepared phases were studied.
Keywords:
properties amn3v4o12;
pressure phases;
specifics properties;
high pressure;
preparation specifics;
amn3v4o12 high
Journal Title: Russian Journal of Inorganic Chemistry
Year Published: 2017
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Journal Title: Russian Journal of Inorganic Chemistry
Year Published: 2017
Link to full text (if available)
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recommendations!