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Magnesium(II) and cadmium(II) octaphenyltetraazaporphyrinates in metal exchange reaction with MnCl2 in DMSO

Reaction kinetics of metal exchange of Mg(II) and Cd(II) octaphenyltetraazaporphynates with MnCl2 in DMSO has been studied by spectrophotometry. Kinetic parameters of the metal exchange reaction have been determined. Possible… Click to show full abstract

Reaction kinetics of metal exchange of Mg(II) and Cd(II) octaphenyltetraazaporphynates with MnCl2 in DMSO has been studied by spectrophotometry. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric reaction mechanism has been suggested. Effect of solvent and salt solvate nature on the rate of metal exchange reaction has been revealed.

Keywords: mncl2 dmso; exchange reaction; reaction; metal exchange

Journal Title: Russian Journal of Inorganic Chemistry
Year Published: 2017

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