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Synthesis of Boron-Containing Siloxanes by Reaction of Hydroxy-closo-Decaborates with Dihalosilanes

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A new approach to the preparation of boron-containing siloxanes based on cluster boron anions has been suggested. This approach consists in the reaction of hydroxy derivatives of closo-decaborate anion [B10H10–n(OH)n]2–… Click to show full abstract

A new approach to the preparation of boron-containing siloxanes based on cluster boron anions has been suggested. This approach consists in the reaction of hydroxy derivatives of closo-decaborate anion [B10H10–n(OH)n]2– (n = 1, 2) with dihalosilanes SiR2Cl2 (R = CH3, t-C4H9, C6H5). The obtained compounds have been characterized by IR, ESI/MS, and NMR (1H, 11B, 13C) spectroscopy.

Keywords: reaction hydroxy; synthesis boron; containing siloxanes; boron; boron containing

Journal Title: Russian Journal of Inorganic Chemistry
Year Published: 2018

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