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Tin Dioxide-Based Superacid Aerogels Produced Using Propylene Oxide

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Tin dioxide-based aerogels were produced by supercritical drying of gels, synthesized using propylene oxide, in CO2 and isopropanol. Aerogels consisted of nanocrystalline cassiterite and had a specific surface area of… Click to show full abstract

Tin dioxide-based aerogels were produced by supercritical drying of gels, synthesized using propylene oxide, in CO2 and isopropanol. Aerogels consisted of nanocrystalline cassiterite and had a specific surface area of 210–270 m2/g. Sulfation with sulfuryl chloride imparted superacidic properties to the aerogels (the Hammett acidity function H0 reached values within the range – 11.99 ≥ H0 ≥ –12.7). Superacid SnO2 aerogels demonstrated high catalytic activity in 1-hexene oligomerization and isomerization.

Keywords: tin dioxide; dioxide based; using propylene; aerogels produced; propylene oxide

Journal Title: Russian Journal of Inorganic Chemistry
Year Published: 2018

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