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Formation of Intermediate Phases during Crystallization of Aluminophosphate and Silicoaluminophosphate Sieves with the AEL Structure

Abstract Using X-ray powder diffraction analysis, 27 Al and 31 P magic angle spinning nuclear magnetic resonance, and nitrogen adsorption–desorption, it has been shown that, during the crystallization of AlPO… Click to show full abstract

Abstract Using X-ray powder diffraction analysis, 27 Al and 31 P magic angle spinning nuclear magnetic resonance, and nitrogen adsorption–desorption, it has been shown that, during the crystallization of AlPO 4 -11 and SAPO-11 molecular sieves, the use of pseudoboehmite as an aluminum source leads to the formation of intermediate phases, which are crystalline aluminophosphates AlPO 4 · 2H 2 O and isostructural silicoaluminophosphates with a mesoporous structure.

Keywords: phases crystallization; structure; intermediate phases; formation intermediate

Journal Title: Petroleum Chemistry
Year Published: 2020

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