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The possibility of the photoelectrochemical reaction of acetate and trifluoroacetate oxidation to yield the corresponding hydrocarbons and perfluorocarbons on UV illumination of a film of nanosized titania n-TiO2 is demonstrated… Click to show full abstract
The possibility of the photoelectrochemical reaction of acetate and trifluoroacetate oxidation to yield the corresponding hydrocarbons and perfluorocarbons on UV illumination of a film of nanosized titania n-TiO2 is demonstrated by the methods of cyclic voltammetry and preparative photoelectrolysis. Thus, the use of solar energy makes it possible to synthesize the Kolbe reaction products at substantially lower potentials on electrodes-catalysts containing no platinum.
Keywords:
tio2;
synthesis thin;
thin film;
kolbe synthesis;
photoelectrocatalytical kolbe;
film
Journal Title: Russian Journal of Electrochemistry
Year Published: 2017
Link to full text (if available)
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Journal Title: Russian Journal of Electrochemistry
Year Published: 2017
Link to full text (if available)
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recommendations!