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Potentiometric Cross-Sensitive Sensors Based on Perfluorinated Membranes Treated at Different Relative Humidity for Codetermination of Cations and Anions in Alkaline Solutions of Amino Acids

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The results of studying characteristics of potentiometric DP-sensors (sensors with the Donnan potential as their analytical signal) are presented for alkaline solutions of a sulfur-containing amino acid with perfluorosulfonic cation… Click to show full abstract

The results of studying characteristics of potentiometric DP-sensors (sensors with the Donnan potential as their analytical signal) are presented for alkaline solutions of a sulfur-containing amino acid with perfluorosulfonic cation exchange membranes subjected to thermal treatment and mechanical deformation at different relative humidity. Correlation between the distribution of sensitivity of DP-sensors towards cations and anions and diffusion permeability of membranes was found. A multisensor system including two DP-sensors based on membranes with optimized properties and a glass electrode for codetermination of potassium cations and amino acid anions and zwitterions in solutions at pH >7 are developed.

Keywords: alkaline solutions; sensors based; cations anions; relative humidity; different relative

Journal Title: Russian Journal of Electrochemistry
Year Published: 2017

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