Abstract The conversion of alcohols into nitriles was studied under conditions of indirect electrochemical oxidation with a catalytic system 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl–potassium iodide–pyridine in a two-phase aqueous organic medium of methylene chloride–aqueous… Click to show full abstract
Abstract The conversion of alcohols into nitriles was studied under conditions of indirect electrochemical oxidation with a catalytic system 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxyl–potassium iodide–pyridine in a two-phase aqueous organic medium of methylene chloride–aqueous sodium hydrocarbonate (pH 8.6) in the presence of hydroxylamine as a source of nitrogen. The desired products were obtained with yields of up to 70%.
Journal Title: Russian Journal of Electrochemistry
Year Published: 2020
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