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Kinetics of the growth of filamentary KH2PO4 crystals on a seed crystal

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At oversaturations exceeding the inert range end for face {101} due to the presence of admixture Al(NO3)3 · 9H2O, a new phase is observed during the growth of this face… Click to show full abstract

At oversaturations exceeding the inert range end for face {101} due to the presence of admixture Al(NO3)3 · 9H2O, a new phase is observed during the growth of this face in the form of filamentary crystals. Some experimental dependences of the growth rate of filamentary potassium dihydrophosphate (KH2PO4) crystals on the oversaturation have been obtained at different admixture concentrations. The growth of filamentary crystals occurs by the mechanism of two-dimensional nucleation. Their formation is governed by the effect of [AlHPO4]+ complexes in the form of Cabrera and Vermilyea stoppers.

Keywords: seed; growth filamentary; kinetics growth; growth; kh2po4 crystals

Journal Title: Physics of the Solid State
Year Published: 2017

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