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Temperature-Phase Dependence of the Vibration Spectrum and Orientation Mobility of the Tetrafluoroborate Ion in n-Bu4NBF4 Organic Salt

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The structural and dynamic properties of a tetrafluoroborate ion in n-Bu4NBF4 organic salt at different temperatures and phase states were studied by oscillation spectroscopy methods. The results of calculations of… Click to show full abstract

The structural and dynamic properties of a tetrafluoroborate ion in n-Bu4NBF4 organic salt at different temperatures and phase states were studied by oscillation spectroscopy methods. The results of calculations of the energy and relaxation parameters have shown that in the plastic phase, a $${\text{BF}}_{4}^{ - }$$ ion is characterized by a low reorientation energy as compared with that of the crystalline phase.

Keywords: phase; tetrafluoroborate ion; organic salt; ion; bu4nbf4 organic; ion bu4nbf4

Journal Title: Physics of the Solid State
Year Published: 2018

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