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Influence of hydrogen on the thermoelectric voltage signal in a Pt/WOx/6H-SiC/Ni/Pt layered structure

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The possibility of detecting H2 by registering the thermal electromotive force signal, which arises between the surfaces of 6H-SiC plates with a thickness of 400 μm, is established. The working… Click to show full abstract

The possibility of detecting H2 by registering the thermal electromotive force signal, which arises between the surfaces of 6H-SiC plates with a thickness of 400 μm, is established. The working surface of the plates is modified by deposition of a WOx film and catalytic Pt. An ohmic contact (Ni/Pt) is created on the rear surface of the plate, and this surface is maintained at a stabilized temperature of 350°C. The temperature gradient through the plate thickness arises due to the cooling of the working surface with the air medium. The delivery of H2 into this medium up to a concentration of 2% gives rise to a 15-fold increase in the electric signal, which considerably exceeds the Pt/WOx/SiC/Ni/Pt system’s response registered in the usual way by measuring the current–voltage dependence. In this case, an additional power source for the registration of the thermal electromotive force is not required.

Keywords: voltage; surface; hydrogen thermoelectric; wox sic; influence hydrogen

Journal Title: Technical Physics Letters
Year Published: 2017

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