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Synthesis and Spectral-Luminescent Properties of Zinc Sulfide Nanoparticles in a Perfluorosulfonic Membrane

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Zinc sulfide nanoparticles were synthesized in pores of a perfluorosulfonic membrane by ion exchange fixation of Zn2+ cations followed by the processing with gaseous hydrogen sulfide. Resulting ZnS particles are… Click to show full abstract

Zinc sulfide nanoparticles were synthesized in pores of a perfluorosulfonic membrane by ion exchange fixation of Zn2+ cations followed by the processing with gaseous hydrogen sulfide. Resulting ZnS particles are X-ray amorphous, have a low density, and are clearly expressed in absorption and luminescence spectra. Features of the nanoparticles optical properties were considered in light of electrons photoexcitation on antibonding orbitals (Zn–S)*.

Keywords: perfluorosulfonic membrane; sulfide nanoparticles; synthesis spectral; zinc sulfide; spectral luminescent

Journal Title: Russian Journal of General Chemistry
Year Published: 2018

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