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Benzene Alkylation with Cycloolefins under the Action of [Et3NH]+[Al2Cl7]− Ionic Liquid

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Benzene alkylation with mono- and bicyclic olefins under the action of an inorganic ionic liquid [Et3NH]+[Al2Cl7]− with the formation of benzene cycloalkyl derivatives in 58–98% yield has been performed for… Click to show full abstract

Benzene alkylation with mono- and bicyclic olefins under the action of an inorganic ionic liquid [Et3NH]+[Al2Cl7]− with the formation of benzene cycloalkyl derivatives in 58–98% yield has been performed for the first time. It has been found that the increase in the olefin cycle size improves the selectivity with respect to monocycloalkyl derivatives.

Keywords: benzene; ionic liquid; benzene alkylation; et3nh al2cl7; action

Journal Title: Russian Journal of General Chemistry
Year Published: 2019

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