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It was shown that the direction of the reaction of 2-methyl-1,4-naphthoquinone with H-phosphonium salts obtained from diphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acids depends on the nature of the anion. Structure… Click to show full abstract
It was shown that the direction of the reaction of 2-methyl-1,4-naphthoquinone with H-phosphonium salts obtained from diphenylphosphine and trifluoromethanesulfonic or trifluoroacetic acids depends on the nature of the anion. Structure of the obtained mono- and diphosphinates, as well as the quasi-phosphonium salt, was established by NMR spectroscopy and single crystal X-ray diffraction methods.
Keywords:
phosphonium;
methyl naphthoquinone;
reaction methyl;
naphthoquinone phosphonium;
features reaction;
phosphonium salts
Journal Title: Russian Journal of General Chemistry
Year Published: 2019
Link to full text (if available)
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Journal Title: Russian Journal of General Chemistry
Year Published: 2019
Link to full text (if available)
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recommendations!