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Supramolecular Associates of Nickel(II) Complexes with Nitro-Substituted Tetradentate Schiff Bases

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Abstract Crystal structures of N , N '-ethylenebis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SalEn)] and N , N '-(2,3-dimethylbutane-2,3-diyl)bis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SaltmEn)] were determined by single crystal X-ray diffraction analysis. The [Ni(3-NO 2… Click to show full abstract

Abstract Crystal structures of N , N '-ethylenebis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SalEn)] and N , N '-(2,3-dimethylbutane-2,3-diyl)bis(3-nitrosalicylideneiminato)nickel(II) [Ni(3-NO 2 SaltmEn)] were determined by single crystal X-ray diffraction analysis. The [Ni(3-NO 2 SalEn)] complex forms supramolecular associates in the crystal phase, which affects its solubility, thermogravimetric, and spectral characteristics.

Keywords: complexes nitro; supramolecular associates; nickel complexes; substituted tetradentate; nitro substituted; associates nickel

Journal Title: Russian Journal of General Chemistry
Year Published: 2020

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