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Structural Transformations of a Carbon Nanomaterial under High-Energy Laser Irradiation

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Abstract Pulsed-laser irradiation of a globular turbostratic carbon material under diverse conditions was carried. A TEM examination revealed formation of nanostructured particles (nanocapsules) under exposure to 1064 nm pulsed radiation… Click to show full abstract

Abstract Pulsed-laser irradiation of a globular turbostratic carbon material under diverse conditions was carried. A TEM examination revealed formation of nanostructured particles (nanocapsules) under exposure to 1064 nm pulsed radiation at the power density of 10 8 W/cm 2 , whose increase to 10 11 W/cm 2 led to formation of structures with a higher degree of ordering. Pulsed irradiation of the initial globules at 532 nm wavelength allowed reducing the interplanar spacings of the graphene layers in the resultant nanocapsules from 0.410 to 0.346 nm. The dependence of the maximum heating temperature of the nanoparticles on the power density in the laser spot was analyzed. The influence of the heating temperature of the carbon nanomaterial on its structure and morphology was assessed.

Keywords: transformations carbon; structural transformations; carbon nanomaterial; laser irradiation; irradiation

Journal Title: Russian Journal of General Chemistry
Year Published: 2020

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