Nonionic polyacrylamide with the weight-average molecular mass of 7 MDa was modified by sulfomethylation. The composition of sulfomethylated polyacrylamides was determined by iodometric titration, Fourier IR spectroscopy, thermal gravimetric analysis,… Click to show full abstract
Nonionic polyacrylamide with the weight-average molecular mass of 7 MDa was modified by sulfomethylation. The composition of sulfomethylated polyacrylamides was determined by iodometric titration, Fourier IR spectroscopy, thermal gravimetric analysis, and elemental analysis. The sulfomethylated acrylate polymers containing ≥19.9 mol % sulfo groups are resistant to brines containing up to 70 g L–1 CaCl2 at temperatures of up to 140°С and to hydrothermal treatment at 180°С. As shown by capillary turbulent rheometry under the conditions of thermal, salt, and acid aggressions, at the optimum concentrations of sulfomethylated polyacrylamide in the medium, сopt = 0.025–0.085%, the maximal extent of a decrease in the hydrodynamic resistance, DRmax, remains on the level of 71–80%, and the flow rate increment, ΔQ, is on the level of (22.01–28.85) × 10–6 m3 s–1.
               
Click one of the above tabs to view related content.