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According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular… Click to show full abstract
According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced in situ in the reaction medium. Ethylene was oligomerized in n-hexane on metal chloride complexes produced in situ from Al/Fe alloys and tert-butyl chloride.
Keywords:
formation metal;
situ formation;
chloride complexes;
chloride;
metal chloride
Journal Title: Russian Journal of Applied Chemistry
Year Published: 2017
Link to full text (if available)
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Journal Title: Russian Journal of Applied Chemistry
Year Published: 2017
Link to full text (if available)
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recommendations!