A novel nanostructured hydrotalcite-supported alkali-doped ruthenium-based catalyst is introduced for the direct gas-phase conversion of ethylene to propylene at 70°C and 1 atm. The maximum conversion of ca. 87% was… Click to show full abstract
A novel nanostructured hydrotalcite-supported alkali-doped ruthenium-based catalyst is introduced for the direct gas-phase conversion of ethylene to propylene at 70°C and 1 atm. The maximum conversion of ca. 87% was obtained at the initial time on stream with a 65% selectivity to propylene and a 6% selectivity to butenes via consecutive reactions. Both conversion and selectivity to olefinic products decreased after 24 min of operation, however.
               
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