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Production of Ethylene, CO, and Hydrogen by Oxidative Cracking of Oil Refinery Gas Components

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Flowsheets based on the results of experimental studies and detailed kinetic modeling were suggested for oxidative cracking of oil refinery gas components to obtain ethylene, CO, and hydrogen. The calculations… Click to show full abstract

Flowsheets based on the results of experimental studies and detailed kinetic modeling were suggested for oxidative cracking of oil refinery gas components to obtain ethylene, CO, and hydrogen. The calculations show that oxidative cracking alone does not allow production of ethylene and СО in ratios required for the further catalytic carbonylation and hydroformylation of ethylene. Matrix conversion of a part of oxy-cracking products is suggested as an additional step for producing CO and hydrogen.

Keywords: oil refinery; cracking oil; oxidative cracking; refinery gas; hydrogen; gas components

Journal Title: Russian Journal of Applied Chemistry
Year Published: 2018

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