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Selective Hydrogenation of Phenylacetylene on a Pd-Containing Catalyst Based on a Polymer Layered Substrate

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Abstract A Pd-containing catalyst based on a layered substrate obtained by the polymerization of 2,3,6,7,10,11-hexahydroxytriphenylene and terephthalic aldehyde was developed and studied. The process of liquid-phase hydrogenation of phenylacetylene was… Click to show full abstract

Abstract A Pd-containing catalyst based on a layered substrate obtained by the polymerization of 2,3,6,7,10,11-hexahydroxytriphenylene and terephthalic aldehyde was developed and studied. The process of liquid-phase hydrogenation of phenylacetylene was studied on the obtained catalyst. It was found that high selectivity for styrene (97%) with complete phenylacetylene conversion is achieved at a hydrogen pressure of 0.1 MPa and a temperature of 40˚C. It has been shown that the catalyst exhibits high stability—maintaining conversion and selectivity for 6 cycles.

Keywords: catalyst; hydrogenation phenylacetylene; layered substrate; containing catalyst; phenylacetylene; catalyst based

Journal Title: Russian Journal of Applied Chemistry
Year Published: 2020

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