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Features of Methyl Linoleate Oxidation in Triton X-100 Micellar Buffer Solutions

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Abstract The kinetics of oxygen absorption during the oxidation of methyl linoleate in Triton X-100 micelles has been studied. The order of the reaction with respect to the initiator diminishes… Click to show full abstract

Abstract The kinetics of oxygen absorption during the oxidation of methyl linoleate in Triton X-100 micelles has been studied. The order of the reaction with respect to the initiator diminishes from 1 to 0.6 with an increase in the total content of Triton X-100 per the unit volume of solution, since by the time of reaching the maximum oxygen absorption rate, the system consists of mixed micelles, which intercept the radicals generated by the initiator. The results of the analysis can be used to assess the dynamics of solubilization of hydrophobic substrates for creating a technique to test the antioxidant activity of biologically important compounds.

Keywords: methyl linoleate; linoleate oxidation; features methyl; triton 100; triton

Journal Title: Russian Journal of Applied Chemistry
Year Published: 2020

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