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Effect of the thermal treatment on the phase composition of the surface of coatings based on Si–B–ZrB2 and modified with ZrO2 fibers

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Coatings on graphite that are stable to oxidation and based on the silicon–boron–zirconium boride composite containing from 5 to 50% of fibrous zirconium dioxide as a modifying dopant have been… Click to show full abstract

Coatings on graphite that are stable to oxidation and based on the silicon–boron–zirconium boride composite containing from 5 to 50% of fibrous zirconium dioxide as a modifying dopant have been produced by the suspension–annealing method. A nonporous layer is formed at the zirconium dioxide content ranging from 5 to 15%, while a porous layer is formed at its 50% content. A glass-forming melt, as well as zirconium dioxide and silicate, is formed during thermal treatment as a result of the chemical reactions with the oxygen in air. The zirconium silicate content increases, along with the modifier’s concentration and temperature.

Keywords: effect thermal; zirconium; treatment phase; zirconium dioxide; thermal treatment

Journal Title: Glass Physics and Chemistry
Year Published: 2017

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