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Optic properties of niobium-phosphate glasses containing lithium, sodium, and potassium oxides

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The dependence of the optic properties of niobium-phosphate glasses containing alkali metal oxides on their composition and structural features is investigated. Along with the increase of the niobium oxide content,… Click to show full abstract

The dependence of the optic properties of niobium-phosphate glasses containing alkali metal oxides on their composition and structural features is investigated. Along with the increase of the niobium oxide content, a shift of the optic absorption boundary to the long-wavelength range and a substantial increase of the refraction index (from 1.50 to 1.73) are observed. The increase of the alkali metal mass results in the decrease of the refraction index and a shift to the short-wavelength range. The correlation between the length of polyphosphate groups and the type of alkali oxide is registered: the chain length increases from lithium to potassium.

Keywords: phosphate glasses; properties niobium; glasses containing; niobium phosphate; optic properties

Journal Title: Glass Physics and Chemistry
Year Published: 2017

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