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Thermally Stimulated Evolution of the Surface of Ni- and Cu-Containing Plasma-Electrolytic Oxide Coatings on Titanium

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The effect of the temperature of annealing in air on the surface architecture and composition of oxide layers has been studied. Copper-enriched nanosized crystals of triangular shape are present on… Click to show full abstract

The effect of the temperature of annealing in air on the surface architecture and composition of oxide layers has been studied. Copper-enriched nanosized crystals of triangular shape are present on the surface at the annealing temperatures of 500–700°С. Rectangular nano- and microcrystals of a possible composition of NiWO4 are formed on the surface after annealing at 750–850°С. Nanowhisker brushes, similar in composition to nickel titanates, cover the surface after annealing at 900–950°С. Transformation of the surface architecture and composition on the micro- and nanolevels correlates to the coatings’ activity in the catalysis of the reaction of oxidation of CO to CO2.

Keywords: evolution surface; surface annealing; surface; stimulated evolution; composition; thermally stimulated

Journal Title: Protection of Metals and Physical Chemistry of Surfaces
Year Published: 2019

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