LAUSR

In this paper, we propose a new model of adsorption–desorption (AD) noise in chemoresistive gas sensors by taking into account the polycrystalline structure of the sensing layer and the effect of the adsorbed molecule’s density fluctuation on the grain boundary barrier height. Using Wolkenstein’s isotherm, in the case of dissociative and non-dissociative chemisorption, combined with the electroneutrality, we derive an exact expression for power density spectrum (PDS) of the AD noise generated around one grain. We show that the AD noise generated in the overall sensing layer is a combination of multi-Lorentzian components. The parameters of each Lorentzian depend on the nature of the detected gas, the grain size, and the gas concentration. Moreover, we show that, according to the sensing layer microstructure (distribution of grain sizes in the sensing layer), this combination can lead to a 1/fγ spectrum, and in this case the noise level of the 1/fγ spectrum depends on the nature of the detected gas. The noise modeling presented in this paper confirms that noise spectroscopy is a useful tool for improving the gas sensor selectivity.