LAUSR

The activities and stabilities of non-platinum group metals in forms of monometallic (Mn2O3, Fe2O3, Co3O4, NiO) and bimetallic (NiFe2O4, CoNiO2) oxides were assessed for the oxygen evolution reaction in alkaline media and benchmarked against IrO2. Both half-cell, rotating disc electrode (RDE) apparatus and single-cell, membrane electrode assemblies (MEA) were used to study kinetic and device-level performance in parallel, and to provide insights into the use of these materials in anion exchange membrane (AEM) electrolyzers. Normalization of RDE results by geometric and physical surface areas, double layer capacitance, and metal content probed differences in physically vs. electrochemically accessible surface areas and ensured reported trends were independent of normalization method. The results showed that Ni- and Co- containing materials met or exceeded IrO2 performance in both RDE and MEA testing, Co3O4 deactivated over time-on-stream (1.8 V for 13.5 h) due to oxide and, relatedly, particle growth, NiFe2O4 increased in activity over time-on-stream due to dissolution of Fe and an increased Ni/Fe ratio, and minimization of catalyst layer resistance is an avenue to further increase device-level performance. These results demonstrated the clear viability of non-PGMs use as the anode catalyst in AEM devices.