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A novel PES-C/(GO-COOH/Ce) blended membrane for treating heavy-metal-ion wastewater

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A GO-COOH/Ce complex was introduced into a phenolphthalide polythersulfone (PES-C) matrix to prepare a PES-C/(GO-COOH/Ce) blended membrane by nonsolvent-induced phase transformation (NIPS). FT-IR and EDS analysis confirmed that the GO-COOH/Ce… Click to show full abstract

A GO-COOH/Ce complex was introduced into a phenolphthalide polythersulfone (PES-C) matrix to prepare a PES-C/(GO-COOH/Ce) blended membrane by nonsolvent-induced phase transformation (NIPS). FT-IR and EDS analysis confirmed that the GO-COOH/Ce complex was successfully incorporated into the PES-C matrix. SEM showed that the blended membrane possessed an asymmetric structure with finger-like pores. The best comprehensive performance was obtained for a PES-C/(GO-COOH/Ce) blended membrane prepared using 0.1 wt.% of the GO-COOH/Ce complex in the casting liquid. The specific results for the blended membrane were as follows: the fluxes of pure water and 0.1 g/L lead nitrate solution were 272 L/m2·h and 214 L/m2·h, respectively; the rejection of bovine serum albumin (BSA) was 99.4%; the rejection of lead ions was 96.2%; the moisture content was 10.9%; the contact angle was 67.1°; the Young's modulus was 35.7 MPa; and the flux recovery ratio was 1.5 times higher than that of the pure PES-C membrane. The antibacterial-zone diameters of the PES-C/(GO-COOH/Ce) blended membrane used against Escherichia coli and Staphylococcus aureus were 2.50 cm and 2.88 cm, respectively. A catalytic cleaning test showed a flux recovery ratio of 63% after washing the PES-C/(GO-COOH/Ce) blended membrane with a 0.2 g/L acetic acid solution for 0.5 h.

Keywords: cooh; cooh blended; cooh complex; pes cooh; blended membrane

Journal Title: High Performance Polymers
Year Published: 2022

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