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Thermal desorption-based method for quantifying semi-volatile organic compounds in house dust: Method development and evaluation

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As an important storage medium of semi-volatile organic compounds (SVOC) in indoor environments, house dust has been extensively used to assess the pollution level of indoor SVOC. SVOC in house… Click to show full abstract

As an important storage medium of semi-volatile organic compounds (SVOC) in indoor environments, house dust has been extensively used to assess the pollution level of indoor SVOC. SVOC in house dust are commonly quantified using solvent-extraction methods, which are however solvent-consuming, time-consuming and laborious. Thermal desorption (TD, solvent-free and easy-to-use) is a good alternative to solvent extractions, but its performance for analyzing house dust is still unverified. Therefore, we proposed a TD-based method for quantifying SVOC in house dust by incorporating the TD technique with GC-MS. Laboratory experiments (48 samples with high SVOC concentrations) and field-test experiments (12 samples with low SVOC concentrations) were performed to justify the proposed method by comparing its results to those of a traditional solvent-extraction method (Soxhlet extraction). For laboratory dusts, the accuracy (relative deviation < 20%) and repeatability (relative standard deviation < 13%) of the TD-based method were comparable to the solvent-extraction method. For field-test dusts, higher SVOC concentrations were typically obtained by the TD-based method, implying its superior performance. These results gave evident confidence in the performance of the TD-based method, which facilitated the simple, solvent-free and accurate quantification of SVOC in house dust.

Keywords: semi volatile; based method; house dust; method

Journal Title: Indoor and Built Environment
Year Published: 2023

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