The purpose of this research is to look into the effect of laser surface modification on the hot corrosion and hot corrosion + calcium–magnesium aluminosilicate (CMAS) resistance of YSZ thermal barrier coating.… Click to show full abstract
The purpose of this research is to look into the effect of laser surface modification on the hot corrosion and hot corrosion + calcium–magnesium aluminosilicate (CMAS) resistance of YSZ thermal barrier coating. Metco AMDRY 997 (Ni–22Cr–10Al–Y) powder was coated as a bond coat on the AISI 304L stainless steel substrate using a high-velocity oxy-fuel spray technique. As a ceramic top layer, 204 NS YSZ (ZrO2·8Y2O3) particles were plasma sprayed on the bond coat. Following that, the entire coating surface was treated with a 20-kHz pulsed CO2 laser to increase the coatings’ surface performance. A corrosion test was carried out in a box furnace for 20 h at 1050 °C. SEM images of laser-glazed coatings revealed denser surfaces than those of air-spraying coatings. The laser-modified coating is more resistant to hot corrosion than unmodified coatings. The X-ray diffraction analysis revealed that the reaction between yttria (Y2O3) and V2O5 resulted in the formation of YVO4 crystals as a corrosion product. According to energy dispersive spectroscopy results, laser-glazed coatings reduced molten salt diffusion from surface to bond coat. As a result, laser-glazed coatings demonstrated improved hot corrosion resistance and decreased corrosion products on the bond coat zone. After the hot corrosion test, the laser-treated composite had a 55% lower thermally grown oxide layer than untreated APS YSZ. The optimum laser parameter was used as 77.7 W laser power, 120 mm/s scanning speed, and 215 mm laser distance.
               
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