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A novel holmium–mercury complex: Structure, green photoluminescence, energy transfer mechanism and semiconducting properties

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The complex (Ho(IA)3(H3O)(H2O)) n (0.5nHg2I6) (HIA = isonicotinic acid) has been synthesized via a hydrothermal reaction and has a one-dimensional (1D) chain-like structure. It has an emission band in the… Click to show full abstract

The complex (Ho(IA)3(H3O)(H2O)) n (0.5nHg2I6) (HIA = isonicotinic acid) has been synthesized via a hydrothermal reaction and has a one-dimensional (1D) chain-like structure. It has an emission band in the green region of 542 nm, which could originate from the 5S2 → 5I8 transition of the Ho3+ ion. The compound possesses Commission Internationale de I’Éclairage chromaticity coordinates of (0.2065, 0.4969) and has a wide optical band gap of 2.32 eV, as found by solid-state UV-Vis diffuse reflectance measurements.

Keywords: structure green; novel holmium; holmium mercury; mercury complex; structure; complex structure

Journal Title: Journal of Chemical Research
Year Published: 2019

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