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From coordination polymer to carbon nanotube: Preparation, characterization and rapid adsorption capacity toward organic pollutants

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A CuI coordination polymer based on the N,N’-bis(3-pyridinecarboxamide)-1,4-butane (3-dpyb) ligand, namely [Cu(3-dpyb)0.5Cl], is hydrothermally synthesized and structurally characterized, and is used as a catalyst precursor to synthesize multi-walled carbon nanotubes.… Click to show full abstract

A CuI coordination polymer based on the N,N’-bis(3-pyridinecarboxamide)-1,4-butane (3-dpyb) ligand, namely [Cu(3-dpyb)0.5Cl], is hydrothermally synthesized and structurally characterized, and is used as a catalyst precursor to synthesize multi-walled carbon nanotubes. Interestingly, the as-grown multi-walled carbon nanotubes exhibit high performance in removing dyes from solution and can serve as a low-cost and fast adsorbent. In addition, the adsorption behavior of this new adsorbent fits well with the Freundlich isotherm and the pseudo-second-order kinetic model.

Keywords: polymer carbon; adsorption; coordination polymer; carbon

Journal Title: Journal of Chemical Research
Year Published: 2020

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