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A New Up-conversion Material of Ho3+-Yb3+-Mg2+ Tri-doped TiO2 and Its Applications to Perovskite Solar Cells

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A new up-conversion nanomaterial of Ho3+-Yb3+-Mg2+ tri-doped TiO2 (UC-Mg-TiO2) was designed and synthesized with a sol-gel method. The UC-Mg-TiO2 presented enhanced up-conversion fluorescence by an addition of Mg2+. The UC-Mg-TiO2… Click to show full abstract

A new up-conversion nanomaterial of Ho3+-Yb3+-Mg2+ tri-doped TiO2 (UC-Mg-TiO2) was designed and synthesized with a sol-gel method. The UC-Mg-TiO2 presented enhanced up-conversion fluorescence by an addition of Mg2+. The UC-Mg-TiO2 was utilized to fabricate perovskite solar cells by forming a thin layer on the electron transfer layer. The results display that the power conversion efficiency of the solar cells based on the electron transfer layer with UC-Mg-TiO2 is improved to 16.3 from 15.2% for those without UC-Mg-TiO2. It is demonstrated that the synthesized UC-Mg-TiO2 can convert the near-infrared light to visible light that perovskite film can absorb to improve the power conversion efficiency of the devices.

Keywords: tio2; new conversion; conversion; ho3 yb3; mg2; solar cells

Journal Title: Nanoscale Research Letters
Year Published: 2018

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