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Two Diastereomers of d-Limonene-Derived Cyclic Carbonates from d-Limonene Oxide and Carbon Dioxide with a Tetrabutylammonium Chloride Catalyst

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Two diastereomers of d-limonene-derived five-membered cyclic carbonates were prepared from the corresponding isomers of d-limonene oxide with CO2. Their syntheses were catalyzed by commercially available tetrabutylammonium chloride with high stereoselectivity.… Click to show full abstract

Two diastereomers of d-limonene-derived five-membered cyclic carbonates were prepared from the corresponding isomers of d-limonene oxide with CO2. Their syntheses were catalyzed by commercially available tetrabutylammonium chloride with high stereoselectivity. The reaction behavior dependent on the reaction conditions such as CO2 pressure was clarified.

Keywords: tetrabutylammonium chloride; limonene oxide; two diastereomers; diastereomers limonene; limonene derived; cyclic carbonates

Journal Title: Bulletin of the Chemical Society of Japan
Year Published: 2018

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