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Generation of Active Ruthenium Catalysts for Hydroarylation of C–C Multiple Bonds from Isolated Ru(IV)=O Species Supported on CeO2

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This paper reports that the treatment of Ru/CeO2 with PPh3 and HCHO in 2-methoxyalcohol was an efficient way to generate the catalytically active Ru species for hydroarylation of C-C multiple… Click to show full abstract

This paper reports that the treatment of Ru/CeO2 with PPh3 and HCHO in 2-methoxyalcohol was an efficient way to generate the catalytically active Ru species for hydroarylation of C-C multiple bonds. A variety of alkenes was applicable toward the title reactions. The solid Ru/CeO2 could be recycled for several times.

Keywords: hydroarylation multiple; ruthenium catalysts; multiple bonds; active ruthenium; generation active

Journal Title: Bulletin of the Chemical Society of Japan
Year Published: 2018

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